Features of heavy metal migration in technogenic zones of the Absheron Peninsula
Aliyev Ch.S.1, Kazimova L.A.2*
1 Ministry of Science and Education of the Republic of Azerbaijan, Institute of Geology and Geophysics, Azerbaijan 119, H.Javid ave., Baku, AZ1143
2 Department of Industrial Safety and Labor Protection, Azerbaijan State Oil and Industry University, Azerbaijan 34, Azadlig ave., Baku, AZ1010
*Corresponding author: Latifa.ismaylova@gmail.com
DOI: 10.33677/ggianas20260100167
Summary
One of the principal indicators characterising the intensity of extraction and utilisation of chemical elements is technophilicity, defined as the ratio between the annual extraction or production of an element (tons per year) and its Clarke concentration in the lithosphere. Numerous chemically analogous elements, despite substantial differences in both Clarke values and production volumes, demonstrate similar or comparable degrees of technophilicity. Technophilicity is a highly dynamic parameter that evolves in response to anthropogenic activity. For example, the continuous increase in oil and gas extraction has contributed to the progressive growth of carbon technophilicity. Likewise, the large-scale production of phosphate fertilizers, dolomite, and magnesite has led to a marked increase in the technophilicity of phosphorus and magnesium. The present study involved comprehensive multi-aspect investigations aimed at assessing the distribution patterns of heavy metals across different environmental media. The Absheron Peninsula was selected as the study area, and numerous samples were collected from various oil-contaminated sites throughout the region. The results obtained from the field investigations and subsequent laboratory analyses revealed the accumulation of a wide spectrum of heavy metals in the soils, including Pb, As, Cr, Cu, Zn, Se, Al, Fe, and Mn. Significant correlations identified between soil pH, organic matter content, and the exchangeable and reducible fractions of most heavy metals indicate that the migration behaviour and mobility patterns of these elements can be reliably predicted in advance.
Keywords: soil samples, technophilicity, Clarke values, geochemical characteristics, migration
REFERENCES
Abramovich MV, Aliyev MM, Khain VY (1952) Geology of Azerbaijan. Geomorphology, Stratigraphy. Published by the Academy of Sciences of the Azerbaijan SSR. Baku, p 559 (in Russian)
Ahnstrom ZAS, Parker DR (2001) Cadmium reactivity in metal-contaminated soils using a coupled stable isotope dilution-sequential extraction procedure. Environ Sci Technol 35(1):121–126. https://doi.org/10.1021/es001350o
Aliyev ChS, Kazimova LA (2024) Assessment of a radioecological situation in Azerbaijan, based on spectral analyses of radionuclides. Journal of Environmental Engineering and Science 19 (3):200–205. https://doi.org/10.1680/jenes.23.00048
Aliyev GA (1978) Soils of the Greater Caucasus (within the Azerbaijan SSR). Part I. Elm, Baku, p 158 (in Russian)
Aliyev GA, Volobuev VR (1953) Soils of the Azerbaijan SSR. Azerbaijan SSR Baku, p 450 (in Russian)
Avessalomova IA, Ivanov AN (2019) Biogeochemistry of landscapes of the Matua Island (Central Kuril Islands). Vestnik Moskovskogo universiteta, Seriya 5 Geografiya (5):77–85 (in Russian)
Chen H, Koopal LK, Xiong J, Avena M, Tan W (2017) Mechanisms of soil humic acid adsorption onto montmorillonite and kaolinite. J Colloid Interf Sci 504:457–467. https://doi.org/10.1016/j.jcis.2017.05.078
Cheng W, Lei S, Bian Z, Zhao Y, Li Y, Gan Y (2020) Geographic distribution of heavy metals and identification of their sources in soils near large, open-pit coal mines using positive matrix factorization. J Hazard Mater 387:121–126. https://doi.org/10.1016/j.jhazmat.2019.121666
FAO–ISRIC (1999). Guidelines for profile description. 3rd edition, FAO, Rome, p 70
Geng N, Xia Y, Li D, Bai F, Xu C ( 2024) Migration and transformation of heavy metal and its fate in intertidal sediments: A Review. Processes 12(2):311–324. https://doi.org/10.3390/pr12020311
Huixia Liu, Bingjie Yu, Zongjiu Sun, Panxing He, Yiqiang Dong, Helong Yang (2025) Spatial variability and driving factors of soil pH in the desert grasslands of northern Xinjiang. Environmental Research 276(121489). https://doi.org/10.1016/j.envres.2025.121489
Khalid S, Shahid M, Niazi NK, Murtaza B, Bibi I, Dumat C (2017) A comparison of technologies for remediation of heavy metal contaminated soils. J Geochem Explor 182(B):247–268. https://doi.org/10.1016/j.gexplo.2016.11.021
Luo X, Wu C, Lin Y, Li W, Deng M, Tan J, Xue S. (2023) Soil heavy metal pollution from Pb/Zn smelting regions in China and the remediation potential of biomineralization. J Environ Sci 125:662-677. https://doi.org/10.1016/j.jes.2022.01.029
Milanovsky EE, Khain VE (1963) Essays on the regional geology of the USSR: The geological structure of the Caucasus. Moscow University Press, Moscow, p 378 (in Russian)
Rustamov G, İsmaylova L (2022) Geochemistry landscape classification: toxicity of chemical elements and their impact on human health. Environ Geochem Health 44:631–643. https://doi.org/10.1007/s10653-020-00747-4
World Reference Base for Soil Resources (2022). International soil classification system for naming soils and creating legends for soil maps, 4-th edition, 2022
Yao J, Qian J, Ji D (2025) Machine learning-based analysis of heavy metal migration under acid rain: Insights from the RF and SVM Algorithms. Minerals 15(6) 663. https://doi.org/10.3390/min15060663
Yaroshevsky AA (2006) Abundances of chemical elements in the Earth’s crust. Geochem. Int. 44:48–55. https://doi.org/10.1134/S001670290601006X
DOI: 10.33677/ggianas20260100167